منابع مشابه
Thermal Diffusion of Isotopes in Pure Liquids
A theoretical treatment is given of the recently discovered thermotransport effect in pure liquid metals. The isotope effect is related to the diffusive mass flow by a proportionality factor familiar from electrotransport. The mass flow is given primarily by the temperature dependence of the mean size or amount of density fluctuations in the liquid. Very little activation energy is required for...
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This paper demonstrates the existence of self-thermophoresis, a phenomenon whereby a virtual thermophoretic force arising from a temperature gradient in a quiescent single-component liquid or gas acts upon an individual molecule of that fluid in much the same manner as a "real" thermophoretic force acts upon a macroscopic, non-Brownian body immersed in that same fluid. In turn, self-thermophore...
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The aim of this study is to understand deeper the thermal diffusion transport process (Ludwig-Soret effect) at the microscopic level. For that purpose, the recently developed reverse nonequilibrium molecular dynamics method was used to calculate Soret coefficients of various systems in a systematic fashion. We studied binary Lennard-Jones (LJ) fluids near the triple point (of one of the compone...
متن کاملMulticomponent diffusion in polymeric liquids.
It is shown how the phase-space kinetic theory of polymeric liquid mixtures leads to a set of extended Maxwell-Stefan equations describing multicomponent diffusion. This expression reduces to standard results for dilute solutions and for undiluted polymers. The polymer molecules are modeled as flexible bead-spring structures. To obtain the Maxwell-Stefan equations, the usual expression for the ...
متن کاملThermal Relaxation and Brillouin Scattering in Liquids
Weak coupling of internal degrees of freedom of molecules to the translational degrees of freedom of a fluid results in additional modes of motion for density fluctuations. These new modes affect the spectral distribution of light scattered by density fluctuations so that the Landau-Placzek ratio is not satisfied. The case of thermal relaxation with a single relaxation time is worked out in det...
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ژورنال
عنوان ژورنال: Chemical engineering
سال: 1959
ISSN: 0375-9253
DOI: 10.1252/kakoronbunshu1953.23.446